o-tolyl salicylate

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Chinese factory supply o-tolyl salicylate 617-01-6 in stock with high standard

  • Molecular Formula: C14H12 O3
  • Molecular Weight: 228.247
  • Vapor Pressure: 2.72E-06mmHg at 25°C 
  • Boiling Point: 379.3°C at 760 mmHg 
  • Flash Point: 162.5°C 
  • Density: 1.216g/cm3 

617-01-6 Relevant articles

Synthesis of salicylates from anionically activated aromatic trifluoromethyl group

Lin, Chuankai,Liu, Jin-Biao,Wang, Ruixiang,Xie, Huilin

supporting information, (2021/12/22)

An efficient approach to salicylates via...

Cerium photocatalyzed radical smiles rearrangement of 2-aryloxybenzoic acids

Tripathy, Alisha Rani,Yatham, Veera Reddy,Yedase, Girish Suresh

, p. 25207 - 25210 (2021/08/05)

We report herein a cerium photocatalyzed...

N-Heterocyclic carbene/photo-cocatalyzed oxidative Smiles rearrangement: Synthesis of aryl salicylates from: O -aryl salicylaldehydes

Xia, Zi-Hao,Dai, Lei,Gao, Zhong-Hua,Ye, Song

supporting information, p. 1525 - 1528 (2020/02/13)

The N-heterocyclic carbene/photo-cocatal...

Efficient Aryl Migration from an Aryl Ether to a Carboxylic Acid Group To Form an Ester by Visible-Light Photoredox Catalysis

Wang, Shao-Feng,Cao, Xiao-Ping,Li, Yang

supporting information, p. 13809 - 13813 (2017/10/24)

We have developed a highly efficient ary...

617-01-6 Process route

2-(2-methylphenoxy)benzoic acid
6325-68-4

2-(2-methylphenoxy)benzoic acid

o-tolyl 2-hydroxybenzoate
617-01-6

o-tolyl 2-hydroxybenzoate

Conditions
Conditions Yield
With dipotassium hydrogenphosphate; Lumogen F Orange 240; In acetonitrile; at 40 ℃; for 26h; Irradiation; Inert atmosphere;
92%
With ammonium peroxydisulfate; cerium(III) chloride; sodium hydrogencarbonate; In ethyl acetate; at 35 ℃; for 24h; Irradiation;
80%
With sodium carbonate; 9-(2-mesityl)-10-methylacridinium perchlorate; In water; acetonitrile; at 20 ℃; for 16h; Irradiation;
75%
With dipotassium peroxodisulfate; potassium trifluoroacetate; silver nitrate; In acetonitrile; at 130 ℃; for 36h; Sealed tube; Inert atmosphere;
52%
2-(2-methylphenoxy)benzaldehyde
67698-66-2

2-(2-methylphenoxy)benzaldehyde

o-tolyl 2-hydroxybenzoate
617-01-6

o-tolyl 2-hydroxybenzoate

Conditions
Conditions Yield
With 2-pentafluorophenyl-6,7-dihydro-5H-pyrrolo[2,1-c][1,2,4]triazol-2-ium tetrafluoroborate; 1,4-diaza-bicyclo[2.2.2]octane; oxygen; sodium iodide; 9-(2-mesityl)-10-methylacridinium perchlorate; In dichloromethane; at 20 ℃; for 36h; Schlenk technique; Irradiation;
67%

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